Nanoscale Pasta: Toward Nanoscale Electronics

San Diego, CA, May 17, 2007 – Pasta tastes like pasta – with or without a spiral. But when you jump to the nanoscale, everything changes: carbon nanotubes and nanofibers that look like nanoscale spiral pasta have completely different electronic properties than their non-spiraling cousins. Engineers at UC San Diego, and Clemson University are studying these differences in the hopes of creating new kinds of components for nanoscale electronics.

Transmission electron microscope (TEM) micrograph of a singly wound, coiled carbon nanofiber (NF) synthesized through thermal chemical vapor deposition (CVD)  at high In concentration (In/Fe ratio > 3).

For example, spiral shaped nanotubes could turn out to be important for new kinds of nanoscale switching and memory storage devices.

Prab Bandaru, professor of mechanical and aerospace engineering at UCSD

Bandaru collaborates with Apparao Rao, of Clemson University, on the controlled synthesis of carbon nanotubes with a variety of shapes, including Y-junctions and nanohelices, through chemical vapor deposition processes. Once they are grown, transmission electron microscopy is used to perform structural analyses of the nonlinear nanotubes. The engineers are also investigating nanotube growth mechanisms, defects, nanoscale electrical conduction mechanisms and device modeling. In addition, they are exploring both the layout of electrical and optoelectronic circuits, and the limits of device operation through high frequency measurements.

A mat of nanocoils. Scale bar = 2 micrometers

“Because nanotubes are so small, you need to work at the atomic level to understand and manipulate them,” explained Bandaru. The presence or absence of single carbon atoms at strategic locations within nanotubes determines whether they have a linear or spiral shape.

Work on nonlinear nanowires is already well underway at UCSD and around the world. Bandaru, for example, is the first author on a paper recently published in the Journal of Applied Physics that outlines a mechanism for how carbon nanotubes and nanofibers grow. In particular, the model predicts conditions under which coiling will happen.

“Now that we know the exact conditions under which the helical nanostructures grow, we can exert greater control over the electronic and other properties of nonlinear nanotubes,” said Bandaru.

Exactly where, when and how linear and nonlinear nanotubes will make the leap from the laboratory to the real world is still unclear. Scientists have more to learn about their basic properties, about how to control their growth, and about how to integrate them into devices.

In August 2005, Bandaru made headlines around the world when his work on Y-shaped nanotubes appeared in the journal Nature Materials. Bandaru and colleagues at UCSD’s Jacobs School and Clemson University demonstrated that Y-shaped nanotubes can behave as electronic switches similar to conventional transistors, which are the workhorses of modern microprocessors, digital memory, and application-specific integrated circuits.

Nanotubes, of course, are not the only tiny spiraling structures. DNA and proteins also have helical structures. “It’s gratifying to encounter connections at the nanoscale between biological structures and helices and coils synthesized via chemical vapor deposition,” said Bandaru. “Our future work might improve our understanding of why helices abound in nature.”

Paper Reference: 
P.R. Bandaru  et al, Journal of Applied Physics, vol. 101, no. 9, p 094307, 2007

Funders for research described in Journal of Applied Physics paper:
The National Science Foundation and the Office of Naval Research. 

The authors also appreciate the use of the facilities at the National Center for Electron Microscopy NCEM at the Lawrence Berkeley National Laboratory, Berkeley, CA.